A microporous scandium terephthalate, Sc2(O2CC6H4CO2)3, with high thermal stability

被引:87
作者
Miller, SR
Wright, PA [1 ]
Serre, C
Loiseau, T
Marrot, J
Férey, G
机构
[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland
[2] Univ Versailles, CNRS, Inst Lavoisier, UMR 8637, F-78035 Versailles, France
基金
英国工程与自然科学研究理事会;
关键词
D O I
10.1039/b506677h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A scandium terephthalate with isolated ScO6 octahedra and fully-linked carboxylate groups is prepared hydrothermally and possesses a novel hybrid framework structure with high thermal stability and a pore volume for N-2 adsorption of 0.26 cm(3) g(-1) at 77 K.
引用
收藏
页码:3850 / 3852
页数:3
相关论文
共 20 条
[1]   A new type of material for the recovery of hydrogen from gas mixtures [J].
Atwood, JL ;
Barbour, LJ ;
Jerga, A .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (22) :2948-2950
[2]   Hydrothermal synthesis and structural characterization of four scandium phosphate frameworks [J].
Bull, I ;
Young, V ;
Teat, SJ ;
Peng, LM ;
Grey, CP ;
Parise, JB .
CHEMISTRY OF MATERIALS, 2003, 15 (20) :3818-3825
[3]   Synthesis and crystal structure of the first scandium-containing open framework solid [J].
Bull, I ;
Wheatley, PS ;
Lightfoot, P ;
Morris, RE ;
Sastre, E ;
Wright, PA .
CHEMICAL COMMUNICATIONS, 2002, (11) :1180-1181
[4]   A route to high surface area, porosity and inclusion of large molecules in crystals [J].
Chae, HK ;
Siberio-Pérez, DY ;
Kim, J ;
Go, Y ;
Eddaoudi, M ;
Matzger, AJ ;
O'Keeffe, M ;
Yaghi, OM .
NATURE, 2004, 427 (6974) :523-527
[5]   High-selectivity, high-flux silica membranes for gas separation [J].
de Vos, RM ;
Verweij, H .
SCIENCE, 1998, 279 (5357) :1710-1711
[6]   Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage [J].
Eddaoudi, M ;
Kim, J ;
Rosi, N ;
Vodak, D ;
Wachter, J ;
O'Keeffe, M ;
Yaghi, OM .
SCIENCE, 2002, 295 (5554) :469-472
[7]   A hybrid solid with giant pores prepared by a combination of targeted chemistry, simulation, and powder diffraction [J].
Férey, G ;
Serre, C ;
Mellot-Draznieks, C ;
Millange, F ;
Surblé, S ;
Dutour, J ;
Margiolaki, I .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (46) :6296-6301
[8]   Hydrogen adsorption in the nanoporous metal-benzenedicarboxylate M(OH)(O2C-C6H4-CO2) (M = Al3+, Cr3+), MIL-53 [J].
Férey, G ;
Latroche, M ;
Serre, C ;
Millange, F ;
Loiseau, T ;
Percheron-Guégan, A .
CHEMICAL COMMUNICATIONS, 2003, (24) :2976-2977
[9]   Crystallized frameworks with giant pores:: Are there limits to the possible? [J].
Férey, G ;
Mellot-Draznieks, C ;
Serre, C ;
Millange, F .
ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :217-225
[10]   A rationale for the large breathing of the porous aluminum terephthalate (MIL-53) upon hydration [J].
Loiseau, T ;
Serre, C ;
Huguenard, C ;
Fink, G ;
Taulelle, F ;
Henry, M ;
Bataille, T ;
Férey, G .
CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (06) :1373-1382