Hollow fibre perovskite membranes for oxygen separation

被引:188
作者
Schiestel, T
Kilgus, M
Peter, S
Caspary, KJ
Wang, H
Caro, J
机构
[1] Fraunhofer Inst Interfacial Engn & Biotechnol, IGB, D-70569 Stuttgart, Germany
[2] Uhde GmbH, D-44141 Dortmund, Germany
[3] Leibniz Univ Hannover, Inst Phys Chem & Elektrochem, D-30167 Hannover, Germany
关键词
perovskite hollow fibre; BCFZ; oxygen; gas separation; oxygen ion conductor;
D O I
10.1016/j.memsci.2005.03.035
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Perovskite hollow fibre membranes of the chemical composition BaZrxCoyFezO3-delta (BCFZ) have been developed using a phase inversion spinning process followed by sintering. The BCFZ hollow fibre membranes show an O-2 flux of 7.6 ml/n-tin/cm(2) at 900 degrees C which is the highest value so far known. From the Wagner theory it follows that the O-2 transport through thin walled perovskite hollow fibre membranes is controlled by both vacancy diffusion and interface reactions. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:1 / 4
页数:4
相关论文
共 12 条
  • [1] Bouwmeester H. J. M., 1996, MEMBRANE SCI TECHNOL, V4
  • [2] KILGUS M, 2004, P C EUR HAMB GERM 27
  • [3] Preparation of SrCe0.95Yb0.05O3-α perovskite for use as a membrane material in hollow fibre fabrication
    Liu, SM
    Li, K
    Hughes, R
    [J]. MATERIALS RESEARCH BULLETIN, 2004, 39 (01) : 119 - 133
  • [4] Oxygen selective ceramic hollow fiber membranes
    Liu, SM
    Gavalas, GR
    [J]. JOURNAL OF MEMBRANE SCIENCE, 2005, 246 (01) : 103 - 108
  • [5] Preparation and characterisation of SrCe0.95Yb0.05O2.975 hollow fibre membranes
    Liu, SM
    Tan, XY
    Li, K
    Hughes, R
    [J]. JOURNAL OF MEMBRANE SCIENCE, 2001, 193 (02) : 249 - 260
  • [6] Preparation of LaSrCoFeO3-x membranes
    Luyten, J
    Buekenhoudt, A
    Adriansens, W
    Cooymans, J
    Weyten, H
    Servaes, F
    Leysen, R
    [J]. SOLID STATE IONICS, 2000, 135 (1-4) : 637 - 642
  • [7] TABLET C, 2004, P 6 INT C CAT MEMBR, P211
  • [8] Tan X., 2004, P 6 INT C CAT MEMBR, P70
  • [9] Preparation and characterization of inorganic hollow fiber membranes
    Tan, XY
    Liu, SM
    Li, K
    [J]. JOURNAL OF MEMBRANE SCIENCE, 2001, 188 (01) : 87 - 95
  • [10] Novel and ideal zirconium-based dense membrane reactors for partial oxidation of methane to syngas
    Tong, JH
    Yang, WS
    Cai, R
    Zhu, BC
    Lin, LW
    [J]. CATALYSIS LETTERS, 2002, 78 (1-4) : 129 - 137