Sodium paeoniflorin sulfonate, a process derived artefact from paeoniflorin

被引：44

作者：

Hayes, PY

Lehmann, R

Penman, K

Kitching, W

De Voss, JJ ^{[1
]}

机构：

[1] Univ Queensland, Dept Chem, SMMS, Brisbane, Qld 4072, Australia

[2] Univ Queensland, Dept Chem, MediHerb Res Labs, Brisbane, Qld 4072, Australia

来源：

TETRAHEDRON LETTERS | 2005年 / 46卷 / 15期

基金：

澳大利亚研究理事会;

关键词：

Paeonia lactiflora; paeoniflorin; sodium paeoniflorin; sulfonate; sulfites; NMR;

D O I：

10.1016/j.tetlet.2005.02.082

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Sodium paeoniflorin sulfonate 2 was isolated from processed, but not unprocessed, Paeonia lactiflora roots and characterized by mass spectrometry and NMR spectroscopy. A notable and characteristic downfield shift in the H-1 NMR was observed for the hydrogens to the alkoxysulfonate moiety in 2 and in other model compounds. (c) 2005 Elsevier Ltd. All rights reserved.

引用

收藏

页码：2615 / 2618

页数：4

相关论文

共 21 条

[1] THE MECHANISM OF THE INTERACTION OF SULPHUR DIOXIDE WITH CERTAIN SUGARS [J].

BRAVERMAN, JBS .

JOURNAL OF THE SCIENCE OF FOOD AND AGRICULTURE, 1953, 4 (11) :540-547

[2]

BRAVERMAN JBS, 1961, J FOOD SCI, V26, P249

[3] COMPLEMENTARY EFFECTS OF PAEONIFLORIN AND GLYCYRRHIZIN ON INTRACELLULAR CA2+ MOBILIZATION IN THE NERVE-STIMULATED SKELETAL-MUSCLE OF MICE [J].

DEZAKI, K ;

KIMURA, I ;

MIYAHARA, K ;

KIMURA, M .

JAPANESE JOURNAL OF PHARMACOLOGY, 1995, 69 (03) :281-284

[4] Antihyperglycemic effects of paeoniflorin and 8-debenzoylpaeoniflorin, glucosides from the root of Paeonia lactiflora [J].

Hsu, FL ;

Lai, CW ;

Cheng, JT .

PLANTA MEDICA, 1997, 63 (04) :323-325

[5]

Kim YK, 2000, J AOAC INT, V83, P1149

[6] DEPOLARIZING EFFECTS OF GLYCYRRHIZIN-DERIVATIVES RELATING TO THE BLEND EFFECTS WITH PAEONIFLORIN IN MOUSE DIAPHRAGM MUSCLE [J].

KIMURA, M ;

KIMURA, I ;

MUROI, M ;

NAKAMURA, T ;

SHIBATA, S .

JAPANESE JOURNAL OF PHARMACOLOGY, 1986, 41 (02) :263-265

[7] A novel, nonaqueous method for regeneration of aldehydes from bisulfite adducts [J].

Kjell, DP ;

Slattery, BJ ;

Semo, HJ .

JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (15) :5722-5724

[8] CRYSTAL STRUCTURE OF BENZALDEHYDE-POTASSIUM BISULFITE ADDITION PRODUCT (POTASSIUM ALPHA-HYDROXYBENZYLSULFONATE) [J].

KURODA, T ;

ASHIDA, T ;

SASADA, Y ;

KAKUDO, M .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1967, 40 (06) :1377-+

[9]

LANG HY, 1990, TETRAHEDRON, V46, P3123

[10] Stimulatory effect of paeoniflorin on the release of noradrenaline from ileal synaptosomes of guinea-pig in-vitro [J].

Liu, TP ;

Liu, IM ;

Tsai, CC ;

Lai, TY ;

Hsu, FL ;

Cheng, JT .

JOURNAL OF PHARMACY AND PHARMACOLOGY, 2002, 54 (05) :681-688