Rational design and construction of the frst tetrahedral net with photoluminescent Cu4I4 cubane cluster as the tetrahedral node

被引：125

作者：

Hu, S

Tong, ML ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China

[2] Sun Yat Sen Univ, State Key Lab Optoelect Mat & Technol, Guangzhou 510275, Peoples R China

来源：

DALTON TRANSACTIONS | 2005年 / 07期

关键词：

D O I：

10.1039/b500015g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Solvothermal reaction of CuI with flexible 1,3-bis(4-pyridyl) propane generated the first three-dimensional coordination polymer constructed with the rigid tetrahedrally connected Cu4I4 cluster unit. The net is a rare chiral triple-interpenetrated, quartz net with of vertex symbol 6(4).8(2). The solid-state luminescence spectrum displays a strong red emission band at room temperature (lambda(max) = 601 nm), characteristic of the Cu I cluster centers.

引用

收藏

页码：1165 / 1167

页数：3

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