Raman spectra of polyparaphenylene-based carbon prepared at low heat-treatment temperatures

被引:23
作者
Matthews, MJ [1 ]
Bi, XX [1 ]
Dresselhaus, MS [1 ]
Endo, M [1 ]
Takahashi, T [1 ]
机构
[1] SHINSHU UNIV,FAC ENGN,NAGANO 380,JAPAN
关键词
D O I
10.1063/1.115718
中图分类号
O59 [应用物理学];
学科分类号
摘要
Raman spectroscopy was used to characterize the structural development of polyparaphenylene (PPP) based carbon at various heat treatment temperatures (T-HT), with an emphasis on the low T-HT regime. Experimental data show that PPP-based carbons undergo a smooth transiiton from a mostly PPP polymer-type structure for heat treatments below similar to 750 degrees C to a graphitized structure at a heat treatment temperature of 2700 degrees C. These results give insight into the unusually high specific capacities observed in lithium-PPP systems which are of particular interest for application to Li ion battery technology. (C) 1996 American Institute of Physics.
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页码:1078 / 1080
页数:3
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