Salt effects on Diels-Alder reaction kinetics

被引：218

作者：

Kumar, A ^{[1
]}

机构：

[1] Natl Chem Lab, Div Phys Chem, Pune 411008, Maharashtra, India

来源：

CHEMICAL REVIEWS | 2001年 / 101卷 / 01期

关键词：

D O I：

10.1021/cr990410+

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Diels-Alder reactions were studied with respect to the effects of salt solutions while altering the reaction rates and stereoselectivity products. A solvent medium like low density polyethylene (LDPE) reduced the reaction time and increased the yield of the product. No single theory was found adequate enough to account for the role of the solvents on the Diels-Alder reaction.

引用

页码：1 / 19

页数：19

共 214 条

[81]

Grieco P. A., 1991, ALDRICHIM ACTA, V24, P59

[82]

Grieco P.A., 1998, Organic synthesis in water

[83] MICELLAR CATALYSIS IN THE AQUEOUS INTERMOLECULAR DIELS-ALDER REACTION - RATE ACCELERATION AND ENHANCED SELECTIVITY [J].

GRIECO, PA ;

GARNER, P ;

HE, Z .

TETRAHEDRON LETTERS, 1983, 24 (18) :1897-1900

[84] ACID-CATALYZED INTRAMOLECULAR DIELS-ALDER REACTIONS IN LITHIUM PERCHLORATE-DIETHYL ETHER - ENHANCED REACTION-RATES AND DIASTEREOSELECTIVITY [J].

GRIECO, PA ;

HANDY, ST ;

BECK, JP .

TETRAHEDRON LETTERS, 1994, 35 (17) :2663-2666

[85] DRAMATIC RATE ACCELERATIONS OF DIELS-ALDER REACTIONS IN 5-M LITHIUM PERCHLORATE DIETHYL-ETHER - THE CANTHARIDIN PROBLEM REEXAMINED [J].

GRIECO, PA ;

NUNES, JJ ;

GAUL, MD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (11) :4595-4596

[86] TOTAL SYNTHESIS OF DL-QUASSIN [J].

GRIECO, PA ;

FERRINO, S ;

VIDARI, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (25) :7586-7587

[87] AQUEOUS INTERMOLECULAR DIELS-ALDER CHEMISTRY - REACTIONS OF DIENE CARBOXYLATES WITH DIENOPHILES IN WATER AT AMBIENT-TEMPERATURE [J].

GRIECO, PA ;

YOSHIDA, K ;

GARNER, P .

JOURNAL OF ORGANIC CHEMISTRY, 1983, 48 (18) :3137-3139

[88] SODIUM 6-METHOXY-(E,E)-3,5-HEXADIENOATE - A USEFUL DIENE IN THE AQUEOUS DIELS-ALDER REACTION [J].

GRIECO, PA ;

YOSHIDA, K ;

HE, Z .

TETRAHEDRON LETTERS, 1984, 25 (50) :5715-5718

[89] AZA DIELS-ALDER REACTIONS IN WATER - CYCLOCONDENSATION OF C-ACYL IMINIUM IONS WITH CYCLOPENTADIENE [J].

GRIECO, PA ;

LARSEN, SD ;

FOBARE, WF .

TETRAHEDRON LETTERS, 1986, 27 (18) :1975-1978

[90] LITHIUM CATALYZED HETERO-DIELS-ALDER REACTIONS CYCLOCONDENSATION OF N-PROTECTED ALPHA-AMINO ALDEHYDES WITH 1-METHOXY-3-TERT-BUTYLDIMETHYLSILYLOXYBUTADIENE IN THE PRESENCE OF LITHIUM PERCHLORATE [J].

GRIECO, PA ;

MOHER, ED .

TETRAHEDRON LETTERS, 1993, 34 (35) :5567-5570

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