Exo-metal coordination by a tricyclic [{P(μ-N-2-NC5H4)}2(μ-O)]2 dimer in [{P(μ-N-2-NC5H4)}2(μ-O)]2{CuCl•(C5H5N)2}4 {2-NC5H4=2-pyridyl, C5H5N=pyridine)

被引：28

作者：

Bond, AD

Doyle, EL

García, F

Kowenicki, RA

McPartlin, M

Riera, L

Wright, DS

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

[2] Univ N London, Sch Chem, London N7 8DB, England

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 24期

关键词：

D O I：

10.1039/b309842g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The in situ reaction of the phosphazane dimer [ClP(mu-N-2-NC5H4)](2) (2) with CuCl in the presence Of C5H5N/H2O gives the title complex [{P(mu-N-2-NC5H4)}(2)(mu-O)](2)(CuCl.(C5H5N)(2))(4) (1), containing a tricyclic [(P(mu-N-2-NC5H4)}2(mu-O)](2) ligand which is isoelectronic with species of the type [{P(mu-NR))(2)NR](2).

引用

收藏

页码：2990 / 2991

页数：2

相关论文

共 20 条

[11]

SUN EH, 1994, J CHEM SOC CHEM COMM, P237

[12] METAL-ASSISTED FORMATION OF PHOSPHORUS OXYGEN HETEROCYCLIC COMPLEXES [J].

SUN, XY ;

WONG, EH ;

TURNBULL, MM ;

RHEINGOLD, AL ;

WALTERMIRE, BE ;

OSTRANDER, RL .

ORGANOMETALLICS, 1995, 14 (01) :83-97

[13] HALOGENATED DERIVATIVES OF THE DIMOLYBDENUM TETRAPHOSPHOXANE CAGE [J].

TURNBULL, MM ;

VALDEZ, C ;

WONG, EH ;

GABE, EJ ;

LEE, FL .

INORGANIC CHEMISTRY, 1992, 31 (02) :208-214

[14]

WANG H, 1993, J CHEM SOC CHEM COMM, P35

[15] 2,4,6,8-TETRAKIS(N,N,-DI-ISOPROPYLAMINO)CYCLOTETRAPHOSPHOXANE (PR2INPO)4, A TETRADENTATE LIGAND THAT CHELATES 2 METALS - ASSEMBLAGE OF A P4O4MO2 CAGE STRUCTURE [J].

WONG, EH ;

TURNBULL, MM ;

GABE, EJ ;

LEE, FL ;

LEPAGE, Y .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (14) :776-777

[16] A METAL-COMPLEX OF 2,4,6-TRIS(N,N-DI-ISOPROPYLAMINO)CYCLOTRIPHOSPHOXANE THAT IS AN INTERMEDIATE TO THE P4O4M2 CAGE COMPLEX [J].

WONG, EH ;

GABE, EJ ;

CHARLAND, JP .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (24) :1632-1634

[17] COORDINATED CYCLO-TETRAPHOSPHOXANE AND CYCLO-PENTAPHOSPHOXANE - 2 CONFIGURATIONS OF THE COORDINATED P4O4 RING [J].

WONG, EH ;

GABE, EJ ;

LEE, FL .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (17) :1236-1238

[18] COORDINATION-COMPLEXES DERIVED FROM TRIPHOSPHOXANE, TETRAPHOSPHOXANE, AND PENTAPHOSPHOXANE RINGS [J].

WONG, EH ;

SUN, XY ;

GABE, EJ ;

LEE, FL ;

CHARLAND, JP .

ORGANOMETALLICS, 1991, 10 (09) :3010-3020

[19] 2 APPROACHES TO THE SYNTHESIS OF BIMETALLIC CAGE COMPLEXES OF THE TETRAOXATETRAPHOSPHORINANE [RPO]4 RING [J].

WONG, EH ;

TURNBULL, MM ;

HUTCHINSON, KD ;

VALDEZ, C ;

GABE, EJ ;

LEE, FL ;

LEPAGE, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (25) :8422-8428

[20] DEMETALATION OF A DIMOLYBDENUM CYCLOTETRAPHOSPHOXANE CAGE COMPLEX AND SYNTHESES OF HETEROBIMETALLIC CAGES [J].

YANG, HY ;

WONG, EH ;

RHEINGOLD, AL ;

OWENSWATERMIRE, BE ;

HAGGERTY, BS .

ORGANOMETALLICS, 1994, 13 (12) :4825-4834