An Ionothermal Synthetic Approach to Porous Polyoxometalate-Based Metal-Organic Frameworks

被引：178

作者：

Fu, Hai ^{[1
]}

Qin, Chao ^{[1
]}

Lu, Ying ^{[1
]}

Zhang, Zhi-Ming ^{[1
]}

Li, Yang-Guang ^{[1
]}

Su, Zhong-Min ^{[1
]}

Li, Wen-Liang ^{[1
]}

Wang, En-Bo ^{[1
]}

机构：

[1] NE Normal Univ, Dept Chem, Minist Educ, Key Lab Polyoxometalate Sci, Changchun 130024, Jilin, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 32期

基金：

中国国家自然科学基金;

关键词：

adsorption; copper; ionic liquids; polyoxometalates; porous materials; DETERMINING SURFACE-AREAS; SELECTIVE GAS-ADSORPTION; IONIC LIQUIDS; STRUCTURAL DIVERSITY; DESIGNED SYNTHESIS; BET METHOD; HYDROGEN; ZEOLITES; CLUSTERS; RECOGNITION;

D O I：

10.1002/anie.201202994

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pretty porous POMs: Ionothermal synthesis was applied to prepare porous POM-based open frameworks. The structural integrity remains unchanged until 300 °C; most importantly, the bulky tetrabutylammonium cations within their nanosized channels can be replaced by transition-metal ions through a cation-exchange process, and subsequent gas adsorption measurements confirm their permanent porosity. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：7985 / 7989

页数：5

共 101 条

[1]

*ACC INC, 2005, MAT STUD 4 2

[2]

Ahmed E, 2012, ANGEW CHEM, V124, P314

[3] Ionothermal Synthesis of Polyoxometalates [J].

Ahmed, Ejaz ;

Ruck, Michael .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (02) :308-309

[4]

Aidoudi FH, 2011, NAT CHEM, V3, P801, DOI [10.1038/nchem.1129, 10.1038/NCHEM.1129]

[5] HETEROPOLYTUNGSTATES AS CATALYSTS FOR THE PHOTOCHEMICAL REDUCTION OF OXYGEN AND WATER [J].

AKID, R ;

DARWENT, JR .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (02) :395-399

[6]

An H. Y., 2006, ANGEW CHEM, V118, P918, DOI [10.1002/ange.200503657, DOI 10.1002/(ISSN)1521-3757]

[7] Chiral 3D architectures with helical channels constructed from polyoxometalate clusters and copper-amino acid complexes [J].

An, HY ;

Wang, EB ;

Xiao, DR ;

Li, YG ;

Su, ZM ;

Xu, L .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (06) :904-908

[8]

[Anonymous], 2012, ANGEW CHEM

[9]

[Anonymous], 2007, ANGEW CHEM-GER EDIT, DOI DOI 10.1002/(ISSN)1521-3757

[10]

[Anonymous], ANGEW CHEM

← 1 2 3 4 5 6 7 8 9 10 →