Device characteristics of polymeric Light Emitting Diodes (pLED) with controlled oxidation of the calcium cathode during growth

被引:4
作者
Andersson, GG [1 ]
de Jong, MP [1 ]
van IJzendoorn, LJ [1 ]
van der Gon, AWD [1 ]
Brongersma, HH [1 ]
de Voigt, MJA [1 ]
机构
[1] Eindhoven Univ Technol, NL-5600 MB Eindhoven, Netherlands
关键词
polymer light emitting diodes; organic/inorganic interfaces; poly(phenylene vinylene); elastic recoil detection analysis (ERDA);
D O I
10.1016/S0379-6779(00)00983-8
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The presence of oxygen during the deposition of the calcium electrode of polymeric light-emitting diodes is investigated. The devices are fabricated in an ultraclean setup. We used ITO as anode, OC1C10 PPV as electroluminescent polymer, calcium as cathode and aluminium as protecting layer. The influence of the presence of dry oxygen during deposition is investigated and the exposure of the calcium layer to dry oxygen subsequently to the deposition on the polymer. The change of the structure due to the exposure to oxygen is determined with elastic recoil detection analysis (ERDA) and correlated to the I-V-light characteristics of the devices. Exposure of the devices to oxygen during deposition leads to a decrease in brightness and current with increasing oxygen pressure. The exposure of the calcium to oxygen subsequently to the deposition does not affect the performance of the devices except at calcium layer thicknesses less than 10 nm.
引用
收藏
页码:1675 / 1676
页数:2
相关论文
共 10 条
  • [1] Blom PWM, 1998, POLYM ADVAN TECHNOL, V9, P390, DOI 10.1002/(SICI)1099-1581(199807)9:7<390::AID-PAT795>3.0.CO
  • [2] 2-9
  • [3] Influence of the process vacuum on the device performance of organic light-emitting diodes
    Bohler, A
    Dirr, S
    Johannes, HH
    Ammermann, D
    Kowalsky, W
    [J]. SYNTHETIC METALS, 1997, 91 (1-3) : 95 - 97
  • [4] CALCIUM ELECTRODES IN POLYMER LEDS
    BROMS, P
    BIRGERSSON, J
    JOHANSSON, N
    LOGDLUND, M
    SALANECK, WR
    [J]. SYNTHETIC METALS, 1995, 74 (02) : 179 - 181
  • [5] Magnesium as electrode in polymer LEDs
    Broms, P
    Birgerson, J
    Salaneck, WR
    [J]. SYNTHETIC METALS, 1997, 88 (03) : 255 - 258
  • [6] DEJONG MP, IN PRESS NUCL INSTR
  • [7] THE OXIDATION OF CALCIUM IN DRY OXYGEN
    GREGG, SJ
    JEPSON, WB
    [J]. JOURNAL OF THE CHEMICAL SOCIETY, 1960, (FEB): : 712 - 716
  • [8] The metal-on-polymer interface in polymer light emitting diodes
    Salaneck, WR
    Bredas, JL
    [J]. ADVANCED MATERIALS, 1996, 8 (01) : 48 - &
  • [9] Degradation and failure of MEH-PPV light-emitting diodes
    Scott, JC
    Kaufman, JH
    Brock, PJ
    DiPietro, R
    Salem, J
    Goitia, JA
    [J]. JOURNAL OF APPLIED PHYSICS, 1996, 79 (05) : 2745 - 2751
  • [10] Reduced operating voltage of organic electroluminescent devices by plasma treatment of the indium tin oxide anode
    Steuber, F
    Staudigel, J
    Stössel, M
    Simmerer, J
    Winnacker, A
    [J]. APPLIED PHYSICS LETTERS, 1999, 74 (23) : 3558 - 3560