The effect of particle size and morphology on the rate capability of 4.7 VLiMn1.5+δNi0.5-δO4 spinel lithium-ion battery cathodes

被引：171

作者：

Kunduraci, M. ^{[1
]}

Amatucci, G. G. ^{[1
]}

机构：

[1] State Univ New Jersey, Dept Mat Sci & Engn, Energy Storage Res Grp, N Brunswick, NJ 08902 USA

来源：

ELECTROCHIMICA ACTA | 2008年 / 53卷 / 12期

关键词：

lithium-ion battery; spinel; rate capability; morphology; cation ordering;

D O I：

10.1016/j.electacta.2007.12.057

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The electrochemical inipact of lithiuni-ion diffusivity Oil the discharge rate capabilities of cation ordered (P4(3)32) and disordered (Fd3m) LiMn1.5+delta Ni0.5-delta O4 spinels were studied. Potentiostatic Intermittent Titration (PITT) measurements revealed Lip to 2 orders-of-magnitude lower lithium diffusion coefficient for the ordered spinet polymorph. The optimum structure of the high voltage spinel is resolved with respect to these ionic studies and our previous electronic transport studies. Modification of the morphology and pore dimensions was accomplished through the tuning of the ethylene glycol used for the synthesis of nanostructured spinel in the modified Pechini process. Glycol will be shown to play a major role on the energy and power density of LiMn1.5+delta Ni0.5-delta O4 electrodes. (c) 2008 Elsevier Ltd. All rights reserved.

引用

页码：4193 / 4199

页数：7

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