New measurements of the viscosity of diisodecyl phthalate using a vibrating wire technique

被引:31
作者
Caetano, FJP
Fareleira, JMNA
Oliveira, CMBP
Wakeham, WA
机构
[1] Univ Tecn Lisboa, Inst Super Tecn, Ctr Quim Estrutural, P-1049001 Lisbon, Portugal
[2] Univ Aberta, R Escola Politecn, P-1269001 Lisbon, Portugal
[3] Univ Southampton, Southampton SO17 1BJ, Hants, England
关键词
D O I
10.1021/je050151n
中图分类号
O414.1 [热力学];
学科分类号
摘要
Diisodecyl plithalate (DIDP) has been proposed as a suitable reference material for industrial application in the region of moderately high viscosity. The paper reports a new set of viscosity measurements of a 99.5 % GC sample of this substance, which are directly traceable to the primary standard reference value the viscosity of water at 293.15 K. The present measurements, performed with a vibrating-wire sensor, were carried out at atmospheric pressure over the temperature range (283 to 313) K. Over this temperature range, the viscosity varies from approximately (37 to 267) mPa center dot s. The measurements have been carried out with an instrument that has already been the subject of improvement since the first measurements were performed, and it relies upon calibration exclusively against the primary standard of viscometry. The estimated overall uncertainty of the results does not exceed 1 %, over the whole range of the measurements and, for the results obtained at temperatures in the vicinity of 293 K, is +/- 0.8 %. The higher quality of the present measurements, and their direct traceability to the primary reference value for viscosity, justifies the replacement of our earlier set of preliminary data on DIDP viscosity.
引用
收藏
页码:1875 / 1878
页数:4
相关论文
共 16 条
[1]  
[Anonymous], 3666 ISOTR
[2]  
BAUER H, COMMUNICATION
[3]   Validation of a vibrating-wire viscometer:: Measurements in the range of 0.5 to 135 mPa•s [J].
Caetano, FJP ;
Fareleira, JMNA ;
Oliveira, CMBP ;
Wakeham, WA .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2005, 50 (01) :201-205
[4]   Viscosity of di-isodecylphthalate: A potential standard of moderate viscosity [J].
Caetano, FJP ;
Fareleira, JMNA ;
Oliveira, CMBP ;
Wakeham, WA .
INTERNATIONAL JOURNAL OF THERMOPHYSICS, 2004, 25 (05) :1311-1322
[5]   Viscosity measurements of liquid toluene at low temperatures using a dual vibrating-wire technique [J].
Caetano, FJP ;
da Mata, JLC ;
Fareleira, JMNA ;
Oliveira, CMBP ;
Wakeham, WA .
INTERNATIONAL JOURNAL OF THERMOPHYSICS, 2004, 25 (01) :1-11
[6]  
CAETANO FJP, 2005, 17 EUR C THERM PROP
[7]   Gas chromatography-mass spectrometry determination of the migration of phthalate plasticisers from polyvinyl chloride toys and childcare articles [J].
Earls, AO ;
Axford, IP ;
Braybrook, JH .
JOURNAL OF CHROMATOGRAPHY A, 2003, 983 (1-2) :237-246
[8]  
FROBA AP, 2003, COMMUNICATION
[9]   Social and economic interest in the control of phthalic acid esters [J].
Gómez-Hens, A ;
Aguilar-Caballos, MP .
TRAC-TRENDS IN ANALYTICAL CHEMISTRY, 2003, 22 (11) :847-857
[10]  
MUNN SJ, 2003, 20785EN EUR, V36