Synthesis, structure, and reaction of the tetrahydroxycyclotetrasiloxane, [(i-Pr)(OH)SiO]4

被引：73

作者：

Unno, M ^{[1
]}

Takada, K ^{[1
]}

Matsumoto, H ^{[1
]}

机构：

[1] Gunma Univ, Fac Engn, Dept Appl Chem, Gunma 3760052, Japan

来源：

CHEMISTRY LETTERS | 1998年 / 06期

关键词：

D O I：

10.1246/cl.1998.489

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

cis,cis,cis-1,3,5,7-Tetrahydroxy-1,3,5,7-tetraisopropylcyclo- tetrasiloxane (1) was synthesized. The X-ray crystallography of 1 revealed that four molecules of 1 and four molecules of water compose a cluster in the lattice. Dehydration of 1 with N,N'-dic yclohexylcarbodiimide (DCC) gave octa(isopropylsilsesquioxane) in good yield.

引用

页码：489 / 490

页数：2

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