Transition-metal-catalyzed C-C bond formation through the fixation of carbon dioxide

被引：784

作者：

Huang, Kun ^{[1
]}

Sun, Chang-Liang ^{[1
]}

Shi, Zhang-Jie ^{[1
,2
]}

机构：

[1] Peking Univ, Minist Educ, Key Lab Bioorgan Chem & Mol Engn, Coll Chem,BNLMS, Beijing 100871, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

CHEMICAL SOCIETY REVIEWS | 2011年 / 40卷 / 05期

关键词：

CROSS-COUPLING REACTION; DIMETHYL CARBONATE; H BONDS; ALKYL-HALIDES; NICKEL(0)-CATALYZED CYCLOADDITION; ELECTROCHEMICAL CARBOXYLATION; ORGANOMETALLIC CHEMISTRY; CYCLIC CARBONATES; CO2; COMPLEXES;

D O I：

10.1039/c0cs00129e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Carbon dioxide is an important carbon source in the atmosphere and is "problematic" toward the activities of human beings. Although carbon dioxide is a cheap, abundant and relatively nontoxic C1 source, its chemical transformations have not been widely developed so far and are still far from synthetic applications, especially in the construction of the C-C bond. This critical review summarizes the recent advances on transition-metal-catalyzed C-C bond formation through the fixation of carbon dioxide and their synthetic applications (124 references).

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页码：2435 / 2452

页数：18

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