Ni(0)-promoted hydroxycarboxylation of 1,2-dienes by reaction with CO2 and O2

被引：30

作者：

Aoki, Masao ^{[1
]}

Izumi, Sawa ^{[1
]}

Kaneko, Motomu ^{[1
]}

Ukai, Kazutoshi ^{[1
]}

Takaya, Jun ^{[1
]}

Iwasawa, Nobuharu ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Chem, Meguro Ku, Tokyo 1528551, Japan

来源：

ORGANIC LETTERS | 2007年 / 9卷 / 07期

关键词：

D O I：

10.1021/ol070038h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel method for the preparation of hydroxy carboxylic acid derivatives has been developed by O-2-oxidation of pi-allylnickel intermediates generated by Ni(0)-mediated coupling of 1,2-dienes with CO2.

引用

页码：1251 / 1253

页数：3

共 33 条

[1] Bidentate amidine ligands for nickel(0)-mediated coupling of carbon dioxide with unsaturated hydrocarbons
Aoki, M
Kaneko, M
Izumi, S
Ukai, K
Iwasawa, N
[J]. CHEMICAL COMMUNICATIONS, 2004, (22) : 2568 - 2569
[2] Billington D. C., 1991, COMPREHENSIVE ORGANI, V3, P423
[3] PI-ALLYLNICKEL HALIDES AS SELECTIVE REAGENTS IN ORGANIC-SYNTHESIS
BILLINGTON, DC
[J]. CHEMICAL SOCIETY REVIEWS, 1985, 14 (01) : 93 - 120
[4] OXANICKELACYCLOPENTENE DERIVATIVES FROM NICKEL(0), CARBON-DIOXIDE, AND ALKYNES
BURKHART, G
HOBERG, H
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1982, 21 (01): : 76 - 76
[5] DERIEN S, 1990, SYNLETT, P361
[6] ELECTROCHEMICAL INCORPORATION OF CARBON-DIOXIDE INTO ALKENES BY NICKEL-COMPLEXES
DERIEN, S
CLINET, JC
DUNACH, E
PERICHON, J
[J]. TETRAHEDRON, 1992, 48 (25) : 5235 - 5248
[7] Steric effects in the aerobic oxidation of π-allylnickel(II) complexes with N-heterocyclic carbenes
Dible, Benjamin R.
Sigman, Matthew S.
[J]. INORGANIC CHEMISTRY, 2006, 45 (20) : 8430 - 8441
[8] Unusual reactivity of molecular oxygen with π-allylnickel(N-heterocyclic carbene) chloride complexes
Dible, BR
Sigman, MS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (04) : 872 - 873
[9] Cyclopentenones from carbonylative cycloaddition of Mackenzie's allyl nickel complexes and acetylenes
García-Gómez, G
Moretó, JM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (04) : 878 - 879
[10] Kinetic analysis of the reaction of isoprene with carbon dioxide and a nickel(0) complex
Geyer, C
Schindler, S
[J]. ORGANOMETALLICS, 1998, 17 (20) : 4400 - 4405

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