Model systems for flavoenzyme activity: Site-isolated redox behavior in flavin-functionalized random polystyrene copolymers

被引：48

作者：

Carroll, JB ^{[1
]}

Jordan, BJ

Xu, H

Erdogan, B

Lee, L

Cheng, L

Tiernan, C

Cooke, G

Rotello, VM

机构：

[1] Univ Massachusetts, Dept Chem, Amherst, MA 01003 USA

[2] Heriot Watt Univ, Sch Engn & Phys Sci, Ctr Biomimet Design & Synth, Edinburgh EH14 4AS, Midlothian, Scotland

来源：

ORGANIC LETTERS | 2005年 / 7卷 / 13期

关键词：

D O I：

10.1021/ol0505407

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A model system has been developed to study the redox behaviors of flavin derivatives appended onto random polystyrene copolymers through "click" chemistry strategies. The results demonstrate that flavin units attached onto polymers exhibit site-isolated redox behaviors, yielding new materials with electrochemically tunable associations (K(a)(ox) = 450 M(-1), k(a)(red) = 18 200 M(-1)) to complementary diamiclopyridine (DAP) functionality.

引用

页码：2551 / 2554

页数：4

共 33 条

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[Anonymous], 1999, Supramolecular electrochemistry

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