A basket tetradecavanadate cluster with blue luminescence

被引：193

作者：

Chen, L

Jiang, FL

Lin, ZZ

Zhou, YF

Yue, CY

Hong, MC ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Fujian 350002, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 24期

关键词：

D O I：

10.1021/ja0422209

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A blue luminescent tetradecavanadate compound, [Et4N]5[V14O36Cl], has been synthesized. It possesses an unprecedented half-open basket framework. Through the {ABAB}-type stacking, the {V14O36} clusters form infinite one-dimensional channels with considerable accessible volume in the crystalline state. Copyright © 2005 American Chemical Society.

引用

页码：8588 / 8589

页数：2

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