Characterisation of CVD-tungsten-alumina cermets for high-temperature selective absorbers

被引:19
作者
Berghaus, A [1 ]
Djahanbakhsh, A [1 ]
Thomas, LK [1 ]
机构
[1] Tech Univ Berlin, Inst Met Werkstoffe Met Phys, D-10623 Berlin, Germany
关键词
tungsten-alumina cermets; absorption;
D O I
10.1016/S0927-0248(97)00219-5
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Solar selective tungsten-alumina cermets were deposited with a low-pressure cold-wall CVD-system utilising the simultaneous pyrolytical decomposition of tungstenhexacarbonyl and aluminiumtriisopropylate (ATI). The deposition results in amorphous W-WOx-Al2O3 films. After a post-deposition annealing in pure hydrogen at 800 degrees C for a maximum of 1 h the films consist of fine grained gamma-alumina and metallic tungsten. The hemispheric reflectivity was measured from 0.2-25 mu m and compared to the emissivity, measured with a thermopile set-up. An absorptivity of 0.85 and an emissivity of 0.04 could be obtained for a single layer on copper substrates, Improvement of the absorption by a gradient of the tungsten content in the layer was investigated. (C) 1998 Published by Elsevier Science B.V. All rights reserved.
引用
收藏
页码:19 / 26
页数:8
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