Novel precursors for the growth of α-In2S3:trisdialkyldithiocarbamates of indium

被引:97
作者
O'Brien, P [1 ]
Otway, DJ [1 ]
Walsh, JR [1 ]
机构
[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England
基金
英国工程与自然科学研究理事会;
关键词
MOCVD; indium sulfide;
D O I
10.1016/S0040-6090(97)00691-3
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Thin films of cubic alpha-In2S3 have been deposited on glass, GaAs(100) and InP(111) by low-pressure metal-organic chemical vapour deposition (LP-MOCVD), using novel air-stable precursors of general formulae In(S2CNMeR)(3) [where R = n-Butyl (compound (1)), n-Hexyl (compound (2))]. The predominant phase in all films grown, regardless of substrate or growth temperature, is alpha-In2S3, oriented in the (hhh) direction. The precursor compounds are considerably more volatile than known dialkyldithiocarbamates of indium. (C) 1998 Elsevier Science S.A.
引用
收藏
页码:57 / 61
页数:5
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