Synthesis, molecular structure, and reactivity of the first strained [2]silanickelocenophane

被引：29

作者：

Braunschweig, Holger ^{[1
]}

Gross, Manuela ^{[1
]}

Radacki, Krzysztof ^{[1
]}

机构：

[1] Julius Maximilians Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

ORGANOMETALLICS | 2007年 / 26卷 / 27期

关键词：

D O I：

10.1021/om701037s

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学]; 081704 [应用化学];

摘要：

The strained ansa-complex [(Me2Si)(2)Cp2Ni] was synthesized by dilithiaton of 1,2-bis(cyclopentadienyl)-1,1,2,2-tetramethyldisilane with BuLi and subsequent reaction with [NiCl2(dme)]. The molecular structure was confirmed by X-ray diffraction analysis. Reaction of the ansa-complex with nickeltetra(tert-butylisonitrile) leads to rearrangement of the ligand framework to form a dinuclear compound.

引用

页码：6688 / 6690

页数：3

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