The chemistry of [1]borametallocenophanes and related compounds

被引：63

作者：

Braunschweig, H

Breitling, FM

Gullo, E

Kraft, M

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, Lehrstuhl Anorgan Chem 2, D-97074 Wurzburg, Germany

[2] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2003年 / 680卷 / 1-2期

基金：

英国工程与自然科学研究理事会;

关键词：

boron; iron; titanium; zirconium; metallocenophanes;

D O I：

10.1016/S0022-328X(03)00402-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Metallocenophanes of early and late transition metals with a variety of different main group element bridges between the two cyclopentadienyl moieties have attracted considerable interest for example as catalysts for the stereospecific generation of polyolefins or as versatile precursors for the synthesis of processable organometallic polymers. The introduction of a borylene moiety as a bridge is a very recent achievement in this area, but has already added some interesting aspects to the rich chemistry of metallocenophanes. (C) 2003 Elsevier Science B.V. All rights reserved.

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页码：31 / 42

页数：12

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