BIS[(TERT-BUTYLAMIDO-DIMETHYLSILYL)CYCLOPENTADIENYL]ZIRCONIUM, (T-C4H9N-SIME2-C5H4)2ZR, A SPIRANOID ZIRCONIUM ACYCLIC COMPOUND

被引：31

作者：

BOHME, U ^{[1
]}

THIELE, KH ^{[1
]}

机构：

[1] MARTIN LUTHER UNIV HALLE WITTENBERG,INST ANORGAN CHEM,GEUSAER STR,D-06217 MERSEBURG,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 472卷 / 1-2期

关键词：

SILYL; ZIRCONIUM; AMIDE; CYCLOPENTADIENYL;

D O I：

10.1016/0022-328X(94)80191-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Independent of the molar ratio of the starting materials bis[tert-butylamido-dimethylsilyl)cyclopentadienyl]zirconium, (t-C4H9N-SiMe2-C5H4)2Zr, is formed as a spiranoide zirconacyclus by reaction of ZrCl4 - 2THF with [t-C4H9N-SiMe2-C5H4]Li2. The constitution was elucidated by means of H-1 and C-13 NMR spectroscopy.

引用

页码：39 / 41

页数：3

共 7 条

[1] BOHME U, IN PRESS Z ANORG ALL
[2] FUNCTIONALIZED CYCLOPENTADIENYL LIGANDS .4. SYNTHESIS AND COMPLEXATION OF LINKED CYCLOPENTADIENYL-AMIDO LIGANDS
OKUDA, J
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[3] CRYSTAL-STRUCTURE OF BIS(1,2-DI-ISOPROPYL-CYCLOPENTADIENYL)ZIRCONIUM DICHLORIDE, C22H34CL2ZR
PETERS, K
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VONSCHNERING, HG
BOEHME, U
THIELE, KH
[J]. ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1992, 198 (3-4): : 285 - 287
[4] CRYSTAL-STRUCTURE OF BIS(1,2,4-TRI-ISOPROPYL-CYCLOPENTADIENYL)ZIRCONIUM DICHLORIDE, C28H46CL2ZR
PETERS, K
PETERS, EM
VONSCHNERING, HG
BOEHME, U
THIELE, KH
[J]. ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1992, 198 (3-4): : 288 - 290
[5] [((ETA-5-C5ME4)ME2SI(ETA-1-NCME3))(PME3)SCH]2 - A UNIQUE EXAMPLE OF A SINGLE-COMPONENT ALPHA-OLEFIN POLYMERIZATION CATALYST
SHAPIRO, PJ
BUNEL, E
SCHAEFER, WP
BERCAW, JE
[J]. ORGANOMETALLICS, 1990, 9 (03) : 867 - 869
[6] SYNTHESIS AND MOLECULAR-STRUCTURE OF [1,3-(ME3SI)2C5H3](ME3SIC5H4)ZRCL2
THIELE, KH
BOHME, U
PETERS, K
PETERS, EM
WALZ, L
VONSCHNERING, HG
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1993, 619 (04): : 771 - 774
[7] THIELE KH, IN PRESS Z ANORG ALL

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