Self-organized TiO2 nanotube arrays by anodization of Ti substrate:: Effect of anodization time, voltage and medium composition on oxide morphology and photoelectrochemical response

被引:25
作者
Watcharenwong, A.
Chanmanee, W.
de Tacconi, N. R.
Chenthamarakshan, C. R.
Kajitvichyanukul, P.
Rajeshwar, K. [1 ]
机构
[1] Univ Texas, Dept Chem & Biochem, CREST, Arlington, TX 76019 USA
[2] Chulalongkorn Univ, Natl Res Ctr Environm & Hazardous Waste Managemen, Bangkok, Thailand
[3] King Mongkuts Univ Technol, Dept Environm Engn, Bangkok, Thailand
关键词
D O I
10.1557/JMR.2007.0391
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
This study probes the relationship between the morphology of anodic titania (TiO2) layers grown on Ti foil substrates and their subsequent photoelectrochemical response in 0.5 M Na2SO4 supporting electrolyte. The effects of anodization variables (voltage and time) and anodization medium composition [water, glycerol, poly(ethylene glycol), ethylene glycol] along with fluoride ion concentration on the oxide layer of morphology and photoresponse are described. The degree of order of the self organized TiO2 nanotube arrays and the extent to which these arrays organize themselves over the entire substrate surface are key variables dictating the corresponding quality of the resultant photoresponse.
引用
收藏
页码:3186 / 3195
页数:10
相关论文
共 60 条
[1]   Formation of titania nanotubes and applications for dye-sensitized solar cells [J].
Adachi, M ;
Murata, Y ;
Okada, I ;
Yoshikawa, S .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (08) :G488-G493
[2]   Enhancement and limits of the photoelectrochemical response from anodic TiO2 nanotubes -: art. no. 243114 [J].
Beranek, R ;
Tsuchiya, H ;
Sugishima, T ;
Macak, JM ;
Taveira, L ;
Fujimoto, S ;
Kisch, H ;
Schmuki, P .
APPLIED PHYSICS LETTERS, 2005, 87 (24) :1-3
[3]   Self-organized porous titanium oxide prepared in H2SO4/HF electrolytes [J].
Beranek, R ;
Hildebrand, H ;
Schmuki, P .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2003, 6 (03) :B12-B14
[4]   The effect of electrolyte composition on the fabrication of self-organized titanium oxide nanotube arrays by anodic oxidation [J].
Cai, QY ;
Paulose, M ;
Varghese, OK ;
Grimes, CA .
JOURNAL OF MATERIALS RESEARCH, 2005, 20 (01) :230-236
[5]   Atomic layer deposition of SiO2 and TiO2 in alumina tubular membranes:: Pore reduction and effect of surface species on gas transport [J].
Cameron, MA ;
Gartland, IP ;
Smith, JA ;
Diaz, SF ;
George, SM .
LANGMUIR, 2000, 16 (19) :7435-7444
[6]   SILICON QUANTUM WIRE ARRAY FABRICATION BY ELECTROCHEMICAL AND CHEMICAL DISSOLUTION OF WAFERS [J].
CANHAM, LT .
APPLIED PHYSICS LETTERS, 1990, 57 (10) :1046-1048
[7]  
Chen Q, 2002, ADV MATER, V14, P1208, DOI 10.1002/1521-4095(20020903)14:17<1208::AID-ADMA1208>3.0.CO
[8]  
2-0
[9]   Nanoporous TiO2 and WO3 films by anodization of titanium and tungsten substrates:: Influence of process variables on morphology and photoelectrochemical response [J].
de Tacconi, N. R. ;
Chenthamarakshan, C. R. ;
Yogeeswaran, G. ;
Watcharenwong, A. ;
de Zoysa, R. S. ;
Basit, N. A. ;
Rajeshwar, K. .
JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (50) :25347-25355
[10]   Semiconductor nanostructures in an alumina template matrix: micro-versus macro-scale photoelectrochemical behavior [J].
de Tacconi, NR ;
Rajeshwar, K .
ELECTROCHIMICA ACTA, 2002, 47 (16) :2603-2613