Tin- or titanium-catalyzed dimethyl carbonate synthesis from carbon dioxide and methanol: Large promotion by a small amount of triflate salts

被引：71

作者：

Choi, Jun-Chul ^{[1
]}

Kohno, Kazufumi ^{[1
]}

Ohshima, Yoshihiro ^{[1
]}

Yasuda, Hiroyuki ^{[1
]}

Sakakura, Toshiyasu ^{[1
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058565, Japan

来源：

CATALYSIS COMMUNICATIONS | 2008年 / 9卷 / 07期

关键词：

carbon dioxide; dimethyl carbonate; homogeneous catalysis; acidic cocatalyst; green chemistry;

D O I：

10.1016/j.catcom.2008.01.013

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Bu(2)SnO- or Ti(O-i-Pr)(4)-catalyzed dimethyl carbonate (DMC) synthesis starting from methanol, carbon dioxide, and dimethyl ketal was remarkably accelerated by the addition of a small amount of [Ph(2)NH(2)]OTf (N:Sn = 1:10); conventional acids such as H(2)SO(4), HCl, and H(3)PO(4) were not effective to promote the DMC synthesis. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：1630 / 1633

页数：4

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