The "Noncoordinating" anion Tf2N- coordinates to Yb2+:: A structurally characterized Tf2N- complex from the ionic liquid [mppyr][Tf2N]

被引：101

作者：

Mudring, AV

Babai, A

Arenz, S

Giernoth, R

机构：

[1] Univ Cologne, Inst Anorgan Chem, D-50939 Cologne, Germany

[2] Univ Cologne, Inst Organ Chem, D-50939 Cologne, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 34期

关键词：

coordination modes; fluorinated ligands; ionic liquids; lanthanides; rare earth metals;

D O I：

10.1002/anie.200501297

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Not as innocent as it looks: The first anionic Tf2N complex, [Yb(Tf2N)4]2-, has been prepared in the ionic liquid [mppyr][Tf2N] (see crystal structure; blue: N, yellow: S, gray: C, green: F, orange: Yb, red: O; mppyr = 1-methyl-1-propyl-pyrrolidinium, Tf=trifloromethanesulfonyl). The coordination of the presumed noncoordinating (innocent") Tf2N 2- ion could have a decisive influence on reactions in ionic liquids. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA."

引用

收藏

页码：5485 / 5488

页数：4

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