Modification of molybdenum disulfide (2H-MoS2) and synthesis of its intercalation compounds

被引：12

作者：

Golub', A. S. ^{[1
]}

Rupasov, D. P. ^{[2
]}

Lenenko, N. D. ^{[1
]}

Novikov, Yu. N. ^{[1
]}

机构：

[1] Russian Acad Sci, Nesmeyanov Inst Organoelement Chem, Moscow 119991, Russia

[2] Moscow MV Lomonosov State Univ, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2010年 / 55卷 / 08期

基金：

俄罗斯基础研究基金会;

关键词：

MOS2; CATIONS; COPPER;

D O I：

10.1134/S0036023610080024

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We have shown that powdered molybdenum disulfide prepared as a result of the exfoliation (singlelayer dispersion) of a crystalline precursor (2H-MoS2) and subsequent precipitation in an acid medium, is capable of forming intercalation compounds in reacting with salts of copper and tetramethylammonium, as well as diethylamine and triethylamine. We consider factors influencing the composition and type of the alternation of guest and host layers in the resulting layered compounds. Relationships between charge transfer to MoS2 layers and the extraordinary reactivity of its modified species are discussed.

引用

页码：1166 / 1171

页数：6

共 17 条

[1] XAFS studies of soft-heavy-metal-ion-intercalated MxMoS2 (M = Hg2+, Ag+) solids [J].

Allen, PG ;

Gash, AE ;

Dorhout, PK ;

Strauss, SH .

CHEMISTRY OF MATERIALS, 2001, 13 (07) :2257-2265

[2] Toward pillared layered metal sulfides. Intercalation of the chalcogenide clusters Co(6)Q(8)(PR(3))(6) (Q=S, Se, and Te and R=alkyl) into MoS2 [J].

Bissessur, R ;

Heising, J ;

Hirpo, W ;

Kanatzidis, M .

CHEMISTRY OF MATERIALS, 1996, 8 (02) :318-&

[3] IRON-INTERCALATED MOLYBDENUM-DISULFIDE OBTAINED FROM SINGLE-LAYER DISPERSION [J].

DANOT, M ;

MANSOT, JL ;

GOLUB, AS ;

PROTZENKO, GA ;

FABRITCHNYI, PB ;

NOVIKOV, YN ;

ROUXEL, J .

MATERIALS RESEARCH BULLETIN, 1994, 29 (08) :833-841

[4] LITHIUM INTERCALATION VIA N-BUTYLLITHIUM OF LAYERED TRANSITION-METAL DICHALCOGENIDES [J].

DINES, MB .

MATERIALS RESEARCH BULLETIN, 1975, 10 (04) :287-291

[5] INTERCALATION COMPOUNDS OF GRAPHITE [J].

DRESSELHAUS, MS ;

DRESSELHAUS, G .

ADVANCES IN PHYSICS, 1981, 30 (02) :139-326

[6] Structural characterization and thermal stability of MoS2 intercalation compounds [J].

Dungey, KE ;

Curtis, MD ;

Penner-Hahn, JE .

CHEMISTRY OF MATERIALS, 1998, 10 (08) :2152-2161

[7] From single-layer dispersions of molybdenum disulfide towards ternary metal sulfides:: incorporating copper and silver into a MoS2 matrix [J].

Golub, AS ;

Shumilova, IB ;

Zubavichus, YV ;

Slovokhotov, YL ;

Novikov, YN ;

Marie, AM ;

Danot, M .

SOLID STATE IONICS, 1999, 122 (1-4) :137-144

[8] Layered compounds assembled from molybdenum disulfide single-layers and alkylammonium cations [J].

Golub, AS ;

Zubavichus, YV ;

Slovokhotov, YL ;

Novikov, YN ;

Danot, M .

SOLID STATE IONICS, 2000, 128 (1-4) :151-160

[9] Phenanthroline intercalation into molybdenum disulfide [J].

Golub, AS ;

Shumilova, IB ;

Novikov, YN ;

Mansot, JL ;

Danot, M .

SOLID STATE IONICS, 1996, 91 (3-4) :307-314

[10] Exfoliated and restacked MoS2 and WS2:: Ionic or neutral species?: Encapsulation and ordering of hard electropositive cations [J].

Heising, J ;

Kanatzidis, MG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (50) :11720-11732

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