Modification of molybdenum disulfide (2H-MoS2) and synthesis of its intercalation compounds

被引：12

作者：

Golub', A. S. ^{[1
]}

Rupasov, D. P. ^{[2
]}

Lenenko, N. D. ^{[1
]}

Novikov, Yu. N. ^{[1
]}

机构：

[1] Russian Acad Sci, Nesmeyanov Inst Organoelement Chem, Moscow 119991, Russia

[2] Moscow MV Lomonosov State Univ, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2010年 / 55卷 / 08期

基金：

俄罗斯基础研究基金会;

关键词：

MOS2; CATIONS; COPPER;

D O I：

10.1134/S0036023610080024

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We have shown that powdered molybdenum disulfide prepared as a result of the exfoliation (singlelayer dispersion) of a crystalline precursor (2H-MoS2) and subsequent precipitation in an acid medium, is capable of forming intercalation compounds in reacting with salts of copper and tetramethylammonium, as well as diethylamine and triethylamine. We consider factors influencing the composition and type of the alternation of guest and host layers in the resulting layered compounds. Relationships between charge transfer to MoS2 layers and the extraordinary reactivity of its modified species are discussed.

引用

页码：1166 / 1171

页数：6

共 17 条

[11] SINGLE-LAYER MOS2 [J].

JOENSEN, P ;

FRINDT, RF ;

MORRISON, SR .

MATERIALS RESEARCH BULLETIN, 1986, 21 (04) :457-461

[12] PROPERTIES OF HXTAS2 - CORRELATION BETWEEN SUPERCONDUCTING TC AND AN ELECTRONIC INSTABILITY IN LAYER COMPOUNDS [J].

MURPHY, DW ;

DISALVO, FJ ;

HULL, GW ;

WASZCZAK, JV ;

MAYER, SF ;

STEWART, GR ;

EARLY, S ;

ACRIVOS, JV ;

GEBALLE, TH .

JOURNAL OF CHEMICAL PHYSICS, 1975, 62 (03) :967-972

[13] NEUTRON-DIFFRACTION STUDY ON FORMATION AND STRUCTURE OF DXTAS2 AND HXNBS2 [J].

RIEKEL, C ;

REZNIK, HG ;

SCHOLLHORN, R ;

WRIGHT, CJ .

JOURNAL OF CHEMICAL PHYSICS, 1979, 70 (11) :5203-5212

[14] High electronic conductivity molybdenum disulfide-dialkylamino nanocomposites [J].

Sánchez, V ;

Benavente, E ;

Ana, MAS ;

González, G .

CHEMISTRY OF MATERIALS, 1999, 11 (09) :2296-+

[15] Characteristics of electrodeposition of composite coatings based on nanosized molybdenum disulfide and copper [J].

Stepanov, A. A. ;

Esenin, V. N. ;

Golub, A. S. ;

Lenenko, N. D. ;

Makhonina, E. V. ;

Pervov, V. S. ;

Novikov, Yu. N. .

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2008, 53 (05) :686-689

[16] 1T-MOS2, A NEW METALLIC MODIFICATION OF MOLYBDENUM-DISULFIDE [J].

WYPYCH, F ;

SCHOLLHORN, R .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (19) :1386-1388

[17] X-ray absorption fine structure study of the atomic and electronic structure of molybdenum disulfide intercalation compounds with transition metals [J].

Zubavichus, YV ;

Slovokhotov, YL ;

Schilling, PJ ;

Tittsworth, RC ;

Golub, AS ;

Protzenko, GA ;

Novikov, YN .

INORGANICA CHIMICA ACTA, 1998, 280 (1-2) :211-218

← 1 2 →