2-[(Z)-2-(p-anisidino)-3,3,3-trifluoropropenyl]-4,4-dimethyl-2-oxazoline

被引:2
作者
Liu-Gonzalez, M
Sanz-Ruiz, F
Navarro-Martinez, A
de la Torre, MG
Fustero-Lardies, S
机构
[1] Univ Valencia, Fac Fis, Dept Termol, E-46100 Valencia, Spain
[2] Univ Valencia, Fac Farm, Dept Quim Organ, Valencia 46100, Spain
来源
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 1998年 / 54卷
关键词
D O I
10.1107/S0108270197017228
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title compound, C15H17F3N2O2, is a C-protected N-substituted beta-enamino acid derivative. Bond lengths suggest pi conjugation between the oxazoline (4,5-dihydro-1,3-oxazole) ring and the enamine double-bond moiety. Intramolecular hydrogen bonding is found between the N atom attached to the aromatic ring and the heterocyclic N atom. Because of steric hindrance between the aromatic ring and the trifluoromethyl group, the plane of the former adopts an almost perpendicular position with respect to the oxazoline ring plane.
引用
收藏
页码:875 / 877
页数:3
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