Evidence for an organization of nanostructured silica-based hybrid materials prepared by sol-gel polymerization

被引：47

作者：

Ben, F ^{[1
]}

Boury, B ^{[1
]}

Corriu, RJP ^{[1
]}

Le Strat, V ^{[1
]}

机构：

[1] Univ Montpellier 2, UMR 5637, Lab Chim Mol & Organ Solide, F-34095 Montpellier 5, France

来源：

CHEMISTRY OF MATERIALS | 2000年 / 12卷 / 11期

关键词：

D O I：

10.1021/cm0011458

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The nature of the organic group is a key factor in the organization of the gel prepared by sol-gel polycondensation of (MeO)(3)Si-R-Si(OMe)(3) precursors. Whereas isotropic gels are formed with flexible alkyl R groups, anisotropic gels are formed with rigid aryl organic groups. [GRAPHICS]

引用

页码：3249 / +

页数：5

共 25 条

[1] Boury B, 1999, ANGEW CHEM INT EDIT, V38, P3172, DOI 10.1002/(SICI)1521-3773(19991102)38:21<3172::AID-ANIE3172>3.0.CO
[2] 2-3
[3] Structure of silica-based organic-inorganic hybrid xerogel
Boury, B
Corriu, RJP
Delord, P
Le Strat, V
[J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 2000, 265 (1-2) : 41 - 50
[4] Some recent developments of polysilsesquioxanes chemistry for material science
Cerveau, G
Corriu, RJP
[J]. COORDINATION CHEMISTRY REVIEWS, 1998, 178 : 1051 - 1071
[5] Sol-gel process: temperature effect on textural properties of a monophasic hybrid material
Cerveau, G
Corriu, RJP
Framery, E
[J]. CHEMICAL COMMUNICATIONS, 1999, (20) : 2081 - 2082
[6] Influence of the nature of the organic precursor on the textural and chemical properties of silsesquioxane materials
Cerveau, G
Corriu, RJP
Lepeytre, C
Mutin, PH
[J]. JOURNAL OF MATERIALS CHEMISTRY, 1998, 8 (12) : 2707 - 2713
[7] Influence of kinetic parameters on the textural and chemical properties of silsesquioxane materials obtained by sol-gel process
Cerveau, G
Corriu, RJP
Fischmeister-Lepeytre, C
[J]. JOURNAL OF MATERIALS CHEMISTRY, 1999, 9 (05) : 1149 - 1154
[8] COLTRAIN BK, 1996, BETTER CERAMICS CHEM, V435
[9] A new trend in metal-alkoxide chemistry: the elaboration of monophasic organic-inorganic hybrid materials
Corriu, R
[J]. POLYHEDRON, 1998, 17 (5-6) : 925 - 934
[10] EVIDENCE FOR A TEMPLATE EFFECT IN CONTROL OF ORGANIC-INORGANIC HYBRID SOLID FORMATION BY INTERMOLECULAR INTERACTIONS
CORRIU, RJP
MOREAU, JJE
THEPOT, P
MAN, MWC
[J]. JOURNAL OF MATERIALS CHEMISTRY, 1994, 4 (06) : 987 - 989

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