Spectroscopic and electrochemical behavior of the methyl and ethyl derivatives of bis(acetylacetonato) oxovanadium(IV)

被引：8

作者：

Claro, PCD ^{[1
]}

González-Baró, AC ^{[1
]}

Parajón-Costa, BS ^{[1
]}

Baran, EJ ^{[1
]}

机构：

[1] Natl Univ La Plata, Fac Ciencias Exactas, CEQUINOR, CONICET, RA-1900 La Plata, Argentina

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2005年 / 631卷 / 10期

关键词：

oxovanadium(IV); substituted acetylacetonates; vibrational spectra; electronic spectra; electrochemical behavior;

D O I：

10.1002/zaac.200500123

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学]; 081704 [应用化学];

摘要：

The infrared, Raman and electronic spectra of the oxovanadium (IV) complexes of the 3-methyl and 3-ethyl substituted acetylacetone were recorded and discussed in detail, in comparison with that of the bis(acetylacetonato) complex and on the basis of the known structural data of these compounds. The electrochemical behavior of the three complexes was investigated by cyclic voltammetry in DMSO solutions, and the mechanism of the involved processes is briefly discussed. © 2005 WILEY-VCH Verlag GmbH & Co. KGaA.

引用

页码：1903 / 1908

页数：6

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