Practical synthesis of new and highly efficient ligands for the Suzuki reaction of aryl chlorides

被引：242

作者：

Zapf, A

Jackstell, R

Rataboul, F

Riermeier, T

Monsees, A

Fuhrmann, C

Shaikh, N

Dingerdissen, U

Beller, M

机构：

[1] Univ Rostock, Leibniz Inst Organ Katalyse, D-18055 Rostock, Germany

[2] Degussa AG, Creavis Technol & Innovat, Project House Catalysis, D-65926 Frankfurt, Germany

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 01期

关键词：

D O I：

10.1039/b311268n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A practical synthesis of a novel class of phosphine ligands, phosphino substituted N-aryl pyrroles (PAP ligands), has been developed. These ligands are applied in the palladium-catalyzed coupling of a variety of aryl and heteroaryl chlorides with phenylboronic acid showing exceedingly high turnover numbers at mild reaction temperatures and even at room temperature.

引用

收藏

页码：38 / 39

页数：2

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