Catalytic dehydrative allylation of alcohols

被引：118

作者：

Saburi, H ^{[1
]}

Tanaka, S ^{[1
]}

Kitamura, M ^{[1
]}

机构：

[1] Nagoya Univ, Res Ctr Mat Sci, Dept Chem, Nagoya, Aichi 4648602, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 11期

关键词：

allyl ethers; allylation; homogeneous catalysis; quinolinecarboxylic acid; ruthenium;

D O I：

10.1002/anie.200462513

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) An environmentally benign synthesis of allyl ethers has been developed which can be applied to a highly chemoselective protection of hydroxyl groups. A highly efficient [CpRu]-2-quinolinecarboxylic acid (L) catalytic system was successfully employed for the dehydrative allylation of various alcohols without additional activators and solvent (see scheme; R = alkyl, aryl, multifunctional alkyl, Cp = C5H 5). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1730 / 1732

页数：3

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