Efficient synthesis of tris(acetonitrile)-(η5-cyclopentadienyl)ruthenium(II) hexafluorophosphate via ruthenocene

被引：122

作者：

Kündig, EP ^{[1
]}

Monnier, FR ^{[1
]}

机构：

[1] Univ Geneva, Dept Organ Chem, CH-1211 Geneva 4, Switzerland

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2004年 / 346卷 / 08期

关键词：

arene complexes; cyclopentadienyl ligands; ligand exchange; ruthenium; ruthenocene;

D O I：

10.1002/adsc.200404124

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

[Ru(eta(5)-C5H5)(CH3CN)(3)][PF6] (1), a versatile precursor to catalysts containing the CpRu+ complex fragment, can be obtained in high yield via Cp/naphthalene exchange in ruthenocene. This new route via the complex [RuCp(naphthalene)][PF6] (4) avoids both highly toxic thallium reagents and the need for a photoreactor.

引用

页码：901 / 904

页数：4

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