Magnetic metal-organic framework constructed from a paramagnetic metalloligand exhibiting a significant sorption and reversible magnetic conversions

被引：54

作者：

Ryu, Dae Won ^{[1
]}

Lee, Woo Ram ^{[1
]}

Lee, Jin Wuk ^{[1
]}

Yoon, Jung Hee ^{[1
]}

Kim, Hyoung Chan ^{[2
]}

Koh, Eui Kwan ^{[3
]}

Hong, Chang Seop ^{[1
]}

机构：

[1] Korea Univ, Dept Chem BK21, Seoul 136713, South Korea

[2] Natl Fus Res Inst, Taejon 305333, South Korea

[3] Korea Basic Sci Inst, Nanobio Syst Res Team, Seoul 136713, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 46期

关键词：

SINGLE-CHAIN MAGNET; SPIN-CROSSOVER; HYDROGEN ADSORPTION; CARBON-DIOXIDE; TEMPERATURE; CRYSTAL; STORAGE; SURFACE; CO2; CU;

D O I：

10.1039/c0cc03540h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A Co(II)-Cu(II) framework based on a paramagnetic metalloligand [Co(Tt)(2)] shows a permanent porosity with a record high surface area for magnetic MOFs as well as a reversible magnetic transformation between a paramagnetic-like state and a short-range magnetic order in the low-temperature regime upon solvation-desolvation cyclings.

引用

页码：8779 / 8781

页数：3

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