Cyclic Voltammetry in the Absence of Excess Supporting Electrolyte Offers Extra Kinetic and Mechanistic Insights: Comproportionation of Anthraquinone and the Anthraquinone Dianion in Acetonitrile

被引：47

作者：

Belding, Stephen R. ^{[1
]}

Limon-Petersen, Juan G. ^{[1
]}

Dickinson, Edmund J. F. ^{[1
]}

Compton, Richard G. ^{[1
]}

机构：

[1] Univ Oxford, Dept Chem, Phys & Theoret Chem Lab, Oxford OX1 3QZ, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 48期

基金：

英国工程与自然科学研究理事会;

关键词：

anthraquinone; comproportionation; computational chemistry; cyclic voltammetry; reaction mechanisms; LOW IONIC-STRENGTH; POTENTIAL STEP CHRONOAMPEROMETRY; STEADY-STATE VOLTAMMETRY; MIGRATIONAL VOLTAMMETRY; DIFFUSION-COEFFICIENTS; TRANSFER RATES; GENERAL-THEORY; ELECTROCHEMISTRY; REDUCTION; SIMULATION;

D O I：

10.1002/anie.201004874

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Less is more: The use of voltammetry in the total or partial absence of supporting electrolyte provides kinetic and mechanistic information beyond that available from familiar fully supported voltammetry. For example, unsupported voltammetry demonstrates that the comproportionation of anthraquinone and anthraquinone dianion proceeds at a diffusionally controlled rate in acetonitrile, a result which could not be determined from "diffusion- only" voltammetry. Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：9242 / 9245

页数：4

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