Preparation of highly ordered monolithic super-microporous lamellar silica with a room-temperature ionic liquid as template via the nanocasting technique

被引:221
作者
Zhou, Y [1 ]
Antonietti, M [1 ]
机构
[1] Max Planck Inst Colloids & Interfaces, D-14424 Potsdam, Germany
关键词
D O I
10.1002/adma.200305265
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The preparation of a novel monolithic super-microporous lamellar silica with a room-temperature ionic liquid (RTIL) as the template, employing the nanocasting technique was reported. RTILs are organic salts with low melting points, sometimes as low as -96°C. They possess a wide range of liquidus temperatures, in some cases in excess of 400°C. A combination of negligible vapor pressure, high ionic conductivity, and thermal stability makes ionic liquids effective as environmentally friendly organic solvent alternatives for catalysis, electrochemistry, liquid-liquid extraction, and organic liquid-phase reactions.
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收藏
页码:1452 / 1455
页数:4
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