Crystal structure and magnetic exchange in the single chloride-bridged copper(II) chain compound [CuCl2(TzHy)] [TzHy = (4,5-dihydro-1,3-thiazol-2-yl)hydrazine]

被引：26

作者：

Barros-García, FJ ^{[1
]}

Bernalte-García, A ^{[1
]}

Higes-Rolando, FJ ^{[1
]}

Luna-Giles, F ^{[1
]}

Pizarro-Galán, AM ^{[1
]}

Viñuelas-Zahínos, E ^{[1
]}

机构：

[1] Univ Extremadura, Dept Quim Inorgan, Fac Ciencias, E-06071 Badajoz, Spain

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2005年 / 631卷 / 10期

关键词：

crystal structure; copper complex; square pyramidal geometry; magnetism;

D O I：

10.1002/zaac.200500119

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The copper complex [CuCl2(TzHy)] has been synthesized and its crystal structure determined. The coordination complex contains polymeric [CUCl2(TzHy)](n) chains in which the units are linked by p-chloro bridges. The chains run along the crystallographic c axis. The geometry around the copper(II) is best described as distorted square pyramidal. The equatorial positions are occupied by Cl(1) and Cl(2) ligands and one thiazolinic nitrogen atom and another hydrazinic nitrogen atom, from TzHy ligand.

引用

页码：1898 / 1902

页数：5

共 51 条

[1] SYNTHESIS, STRUCTURE, AND SPECTROSCOPIC PROPERTIES OF COPPER(II) COMPOUNDS CONTAINING NITROGEN SULFUR DONOR LIGANDS - THE CRYSTAL AND MOLECULAR-STRUCTURE OF AQUA[1,7-BIS(N-METHYLBENZIMIDAZOL-2'-YL)-2,6-DITHIAHEPTANE]COPPER(II) PERCHLORATE [J].

ADDISON, AW ;

RAO, TN ;

REEDIJK, J ;

VANRIJN, J ;

VERSCHOOR, GC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (07) :1349-1356

[2] The Cambridge Structural Database: a quarter of a million crystal structures and rising [J].

Allen, FH .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 (3 PART 1) :380-388

[3]

AVALOS M, 1992, HETEROCYCLES, V33, P973

[4] Pseudotetrahedral cobalt(II) complexes with thiazoline and thiazine derivative ligands:: synthesis and characterization [J].

Barros-García, FJ ;

Bernalte-García, A ;

Lozano-Vila, AM ;

Luna-Giles, F ;

Viñuelas-Zahínos, E .

POLYHEDRON, 2005, 24 (01) :129-136

[5] Synthesis, crystal structure, spectroscopic and magnetic properties of copper(II) complexes with 2-(2-pyridyl)imino-N-(2-thiazolin-2-yl)thiazolidine (PyTT) [J].

Barros-García, FJ ;

Bernalte-García, A ;

Higes-Rolando, FJ ;

Luna-Giles, F ;

Maldonado-Rogado, MA ;

Viñuelas-Zahínos, E .

INORGANICA CHIMICA ACTA, 2004, 357 (12) :3574-3582

[6] Synthesis and structural characterization of cadmium(II) complexes with 2-(2-pyridyl)imino-N-(2-thiazolin-2-yl)thiazolidine (PyTT) [J].

Barros-García, FJ ;

Bernalte-García, A ;

Higes-Rolando, FJ ;

Luna-Giles, F ;

Pedrero-Marín, R ;

Viñuelas-Zahínos, E .

INORGANICA CHIMICA ACTA, 2004, 357 (05) :1457-1464

[7] Studies of the thermal decomposition of (2-thiazolin-2-yl)hydrazine hydrochloride and some metal derivative complexes [J].

Bernalte-García, A ;

García-Barros, FJ ;

Higes-Rolando, FJ ;

Pizarro-Galán, AM ;

Valenzuela-Calahorro, C .

THERMOCHIMICA ACTA, 1999, 339 (1-2) :95-101

[8] Synthesis and physic-chemical properties of a copper(II) complex with 2-(2-pyridyl)iminotetrahydro-1,3-thiazine hydrochloride-water (1/2) (PyTzHCl • 2H2O).: Crystal structure of PyTz and [{CuCl(PyTz)}2(μ-Cl)2] [J].

Bernalte-Garcia, A ;

García-Barros, FJ ;

Higes-Rolando, FJ ;

Luna-Giles, F ;

Pedrero-Marín, R .

JOURNAL OF INORGANIC BIOCHEMISTRY, 2004, 98 (01) :15-23

[9] Coordination chemistry of thiazoline/thiazolidine derivatives.: I:: Crystal structure of 2-(2-pyridyl)imino-N-(2-thiazolin-2-yl)thiazolidine (PyTT) and study of its interaction with nickel(II) [J].

Bernalte-García, A ;

García-Barros, FJ ;

Higes-Rolando, FJ ;

Luna-Giles, F .

POLYHEDRON, 1999, 18 (22) :2907-2912

[10] The coordination chemistry of (2-thiazolin-2-yl)hydrazine hydrochloride (TzHyHCl) .1. Crystal structure of the ligand and study of its interaction with nickel(II) [J].

BernalteGarcia, A ;

DiazDiez, MA ;

GarciaBarros, FJ ;

HigesRolando, FJ ;

PizarroGalan, AM ;

RomeroGarzon, J ;

ValenzuelaCalahorro, C .

POLYHEDRON, 1996, 15 (10) :1691-1697

← 1 2 3 4 5 6 →