Oxovanadium complexes in catalytic oxidations

被引：239

作者：

da Silva, Jose A. L. ^{[1
]}

Frausto da Silva, Joao J. R. ^{[1
]}

Pombeiro, Armando J. L. ^{[1
]}

机构：

[1] Univ Tecn Lisboa, Inst Super Tecn, Ctr Quim Estrutural, P-1049001 Lisbon, Portugal

来源：

COORDINATION CHEMISTRY REVIEWS | 2011年 / 255卷 / 19-20期

关键词：

Oxovanadium complexes; Catalysis; Oxidations; Alkanes; Olefins; SCHIFF-BASE COMPLEXES; MODIFIED SILICA-GEL; SINGLE-POT HYDROCARBOXYLATION; LIQUID-PHASE OXIDATION; METHYL PHENYL SULFIDE; ALPHA-HYDROXY ESTERS; H BOND ACTIVATION; ALLYLIC ALCOHOLS; VANADIUM COMPLEXES; ASYMMETRIC EPOXIDATION;

D O I：

10.1016/j.ccr.2011.05.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This contribution is an overview on recent advances (since 2000) on the application of oxovanadium complexes as catalysts or mediators for oxidations by molecular oxygen, peroxidative oxygenations (both including epoxidations), halogenations and carboxylations of aliphatic and aromatic hydrocarbons, and/or olefins, toward the syntheses of a variety of organic compounds, such as alcohols, ketones, epoxides, aldehydes, organohalides and orcarboxylic acids. Some of these systems operate in liquid media, whereas others involve VO-catalysts immobilized on solid supports. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：2232 / 2248

页数：17

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