A new vanadium Schiff base complex as catalyst for oxidation of alcohols

被引：41

作者：

Bagherzadeh, Mojtaba ^{[1
]}

Amini, Mojtaba ^{[1
]}

机构：

[1] Sharif Univ Technol, Dept Chem, Tehran, Iran

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2010年 / 63卷 / 21期

关键词：

Bidentate Schiff base; Vanadium complex; Catalytic oxidation; Oxone; CORRESPONDING CARBONYL-COMPOUNDS; BENZYLIC ALCOHOLS; HYDROGEN-PEROXIDE; ORGANIC-SYNTHESIS; LIGANDS; MONONUCLEAR; COPPER(II); KETONES; NICKEL(II); ALDEHYDES;

D O I：

10.1080/00958972.2010.520316

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The monoanionic bidentate Schiff base, N-(phenolyl)-benzaldimine (HL), has been employed to synthesize a new vanadium(IV) complex of general composition [VO(L)2] (where L = O, N donor of Schiff base). The ligand and complex have been fully characterized by elemental analyses, molar conductance data, FT-IR, 1H- and 13C-NMR, and UV-Vis spectroscopies. Oxidation of alcohols to their corresponding aldehydes and ketones was conducted by this complex catalyst using Oxone as oxidant under biphasic reaction conditions (CH2Cl2/H2O) and tetra-n-butylammonium bromide as phase transfer agent under air at room temperature.

引用

收藏

页码：3849 / 3858

页数：10

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