A new and highly effective method for catalytic oxidation of alcohols to the corresponding carbonyl compounds using the tris[(2-oxazolinyl)phenolatolmanganese(III)/Oxone®/n-Bu4NBr oxidation system

被引：35

作者：

Bagherzadeh, M ^{[1
]}

机构：

[1] Sharif Univ Technol, Dept Chem, Tehran, Iran

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 50期

关键词：

Mn-oxazoline complex; alcohol; catalytic oxidation; Oxone (R);

D O I：

10.1016/j.tetlet.2003.10.018

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Oxone(R) (2KHSO(5).KHSO4.K2SO4) in the presence of mer-tris[(2-oxazolinyl)phenolato]manganese(III), Mn(phox)(3), as catalyst under biphasic reaction conditions (CH2Cl2/H2O) and tetra-n-butylammonium bromide as phase transfer agent efficiently oxidises alcohols to their corresponding aldehydes and ketones at room temperature with very short reaction times (5 min) and good to quantitative yields. (C) 2003 Elsevier Ltd. All rights reserved.

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收藏

页码：8943 / 8945

页数：3

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