A new and highly effective method for catalytic oxidation of alcohols to the corresponding carbonyl compounds using the tris[(2-oxazolinyl)phenolatolmanganese(III)/Oxone®/n-Bu4NBr oxidation system

被引：35

作者：

Bagherzadeh, M ^{[1
]}

机构：

[1] Sharif Univ Technol, Dept Chem, Tehran, Iran

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 50期

关键词：

Mn-oxazoline complex; alcohol; catalytic oxidation; Oxone (R);

D O I：

10.1016/j.tetlet.2003.10.018

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Oxone(R) (2KHSO(5).KHSO4.K2SO4) in the presence of mer-tris[(2-oxazolinyl)phenolato]manganese(III), Mn(phox)(3), as catalyst under biphasic reaction conditions (CH2Cl2/H2O) and tetra-n-butylammonium bromide as phase transfer agent efficiently oxidises alcohols to their corresponding aldehydes and ketones at room temperature with very short reaction times (5 min) and good to quantitative yields. (C) 2003 Elsevier Ltd. All rights reserved.

引用

收藏

页码：8943 / 8945

页数：3

相关论文

共 28 条

[11] Synthesis and characterization of the new complex tris [(2-oxazolinyl) phenolate] manganese(III) and its use as a catalyst in oxidation reactions [J].

Hoogenraad, M ;

Ramkisoensing, K ;

Kooijman, H ;

Spek, AL ;

Bouwman, E ;

Haasnoot, JG ;

Reedijk, J .

INORGANICA CHIMICA ACTA, 1998, 279 (02) :217-220

[12]

HUDLICKY M, 1990, OXIDATIONS ORGANIC C, P114

[13] THE OXIDATION OF ORGANIC SUBSTANCES BY POTASSIUM PEROXYMONOSULFATE [J].

KENNEDY, RJ ;

STOCK, AM .

JOURNAL OF ORGANIC CHEMISTRY, 1960, 25 (11) :1901-1906

[14] Oxidation of benzyl alcohols with Oxone® and sodium bromide [J].

Koo, BS ;

Lee, CK ;

Lee, KJ .

SYNTHETIC COMMUNICATIONS, 2002, 32 (14) :2115-2123

[15] Oxidation of alcohols to carbonyl compounds with a new potassium permanganate adsorbed on kieselguhr reagent [J].

Lou, JD ;

Lou, WX .

SYNTHETIC COMMUNICATIONS, 1997, 27 (21) :3697-3699

[16] METALLOPORPHYRINS AS VERSATILE CATALYSTS FOR OXIDATION REACTIONS AND OXIDATIVE DNA CLEAVAGE [J].

MEUNIER, B .

CHEMICAL REVIEWS, 1992, 92 (06) :1411-1456

[17] Phase transfer catalyzed oxidation of alcohols with sodium hypochlorite [J].

Mirafzal, GA ;

Lozeva, AM .

TETRAHEDRON LETTERS, 1998, 39 (40) :7263-7266

[18] Catalytic oxidation of saturated C-H bonds by tetrabutylammonium periodate and manganese porphyrins [J].

Mohajer, D ;

Bagherzadeh, M .

JOURNAL OF CHEMICAL RESEARCH-S, 1998, (09) :556-557

[19] Dirhodium (II) carboxylate-catalysed oxidation of allylic and benzylic alcohols [J].

Moody, CJ ;

Palmer, FN .

TETRAHEDRON LETTERS, 2002, 43 (01) :139-141

[20] Kinetic investigations into the mechanism of peroxosulfate oxidation of Calmagite dye catalysed by manganese(II) ions [J].

Oakes, J ;

Gratton, P ;

Weil, I .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (20) :3805-3809