Synthesis and characterization of the new complex tris [(2-oxazolinyl) phenolate] manganese(III) and its use as a catalyst in oxidation reactions

被引：28

作者：

Hoogenraad, M

Ramkisoensing, K

Kooijman, H

Spek, AL

Bouwman, E

Haasnoot, JG

Reedijk, J

机构：

[1] Leiden Univ, Leiden Inst Chem, Gorlaeus Labs, NL-2300 RA Leiden, Netherlands

[2] Univ Utrecht, Bijvoet Ctr Biomol Res Crystal & Struct Chem, NL-3584 CH Utrecht, Netherlands

来源：

INORGANICA CHIMICA ACTA | 1998年 / 279卷 / 02期

关键词：

manganese complexes; oxazoline complexes; crystal structures; epoxidation;

D O I：

10.1016/S0020-1693(98)00118-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new manganese complex, Mn(phox)(3) (Hphox = 2-(2'-hydroxyphenyl) oxazoline), was synthesized and characterized. The X-ray structure shows the complex to be in a mer configuration with a significant Jahn-Teller distortion. Preliminary results show that this complex is a promising catalyst for the epoxidation of styrene with H2O2. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：217 / 220

页数：4

共 19 条

[1] THE COORDINATION CHEMISTRY OF MIXED PYRIDINE-PHENOL LIGANDS - SYNTHESES AND CRYSTAL-STRUCTURES OF MN(III) AND NI(II) COMPLEXES OF 2-(2-HYDROXYPHENYL) PYRIDINE [J].