Oxidation of benzyl alcohols with Oxone® and sodium bromide

被引：45

作者：

Koo, BS ^{[1
]}

Lee, CK ^{[1
]}

Lee, KJ ^{[1
]}

机构：

[1] Hanyang Univ, Dept Ind Chem, Seoul 133791, South Korea

来源：

SYNTHETIC COMMUNICATIONS | 2002年 / 32卷 / 14期

关键词：

oxidation; benzyl alcohols; Oxone((R)); sodium; bromide;

D O I：

10.1081/SCC-120005418

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of benzyl alcohols with Oxone(R) and sodium bromide in aqueous acetonitrile gave the corresponding benzaldehydes in excellent yields. However, electron-rich benzyl alcohols afforded ring bromination products via bromodecarbonylation of the resulting benzaldehydes.

引用

收藏

页码：2115 / 2123

页数：9

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