Synthesis of nickel(II) triazolenaphthalocyanine and related macrocycles

被引：20

作者：

Nicolau, M ^{[1
]}

Cabezón, B ^{[1
]}

Torres, T ^{[1
]}

机构：

[1] Univ Autonoma Madrid, Dpto Quim Organ, E-28049 Madrid, Spain

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2001年 / 66卷 / 01期

关键词：

D O I：

10.1021/jo001039p

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of novel monbenzotriazolephthalocyanines (3 - 6), low-symmetry phthalocyanine analogues, is described for the first time using a novel and simple stepwise strategy which involves the use of substituted naphthalodinitriles 8-11 and appropriately substituted three-unit compounds such as 7. Belonging to the same family, compound 1, which we have called triazolenaphthalocyanine, has been prepared by a statistical method from compound 2 and 3,5-diamino-1,2,4-triazole. Compound 1 shows a bathochromic shift of the Q-band in UV-vis spectrum due to the fusing of benzene rings to the triazolephthalocyanine core.

引用

页码：89 / 93

页数：5

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