Sawhorse connections in a Ag(I)-nitrite coordination network:: {[Ag(pyrazine)]NO2}∞

被引:56
作者
Blake, AJ
Champness, NR
Crew, M
Parsons, S
机构
[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England
[2] Univ Edinburgh, Dept Chem, Edinburgh EH9 3JJ, Midlothian, Scotland
关键词
D O I
10.1039/a808025i
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The Ag(8) coordination networks, {[Ag(pyrazine)]NO2}(infinity) and {[Ag(4,4'-bipy)]NO2}(infinity) have been constructed in order to investigate the effect of anion upon network topology; an unusual sawhorse connection is observed in the structure of {[Ag(pyrazine)]NO2}(infinity) with the nitrite anion acting to 'block' cis coordination sites.
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收藏
页码:13 / 15
页数:3
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