Synthetic models for non-heme carboxylate-bridged diiron metalloproteins: Strategies and tactics

被引：592

作者：

Tshuva, EY ^{[1
]}

Lippard, SJ ^{[1
]}

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

CHEMICAL REVIEWS | 2004年 / 104卷 / 02期

关键词：

D O I：

10.1021/cr020622y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthetic model chemistry of non-heme carboxylate-bridged metalloproteins was discussed. The structures and oxidation mechanisms of the synthetic inorganic compounds were determined. The processes which proceed via dioxygen activation at the dimetallic center in a biomimetric fashion, and radical reactions that exclude actual participation of the metal active site were also determined. Systems operated in a stoichiometric manner with irreversible decomposition of metal complex were addressed.

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页码：987 / 1011

页数：25

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