Diastereoselective ruthenium-Cp complexation of enantiopure arene compounds possessing stereogenic benzylic alcohol functionalities

被引：18

作者：

Kamikawa, K

Furusyo, M

Uno, T

Sato, Y

Konoo, A

Bringmann, G

Uemura, M ^{[1
]}

机构：

[1] Osaka Prefecture Univ, Fac Integrated Arts & Sci, Dept Chem, Sakai, Osaka 5998531, Japan

[2] Sumitomo Elect Ind Ltd, CAE Res Ctr, Seika, Kyoto 6190237, Japan

[3] Osaka Prefecture Univ, Fac Engn, Dept Mat Sci, Sakai, Osaka 5998531, Japan

[4] Univ Wurzburg, Inst Organ Chem, D-97074 Wurzburg, Germany

来源：

ORGANIC LETTERS | 2001年 / 3卷 / 23期

关键词：

D O I：

10.1021/ol010197f

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Enantiopure (arene)ruthenium compounds possessing a stereogenic benzylic alcohol functionality were stereoselectively synthesized by diastereoselective ruthenium-Cp complexation to a distinct arene face. This diastereoselective ruthenium-Cp complexation was further extended to biaryl compounds linked with a six-membered lactone bridge for the synthesis of enantiomerically pure, axially chiral biaryls.

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页码：3667 / 3670

页数：4

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