SYNTHESIS AND ABSOLUTE STEREOSTRUCTURE OF DINAPHTH[2,1-C1',2'-E]OXEPIN-3-(5H)-ONE

被引：18

作者：

BRINGMANN, G ^{[1
]}

HARTUNG, T ^{[1
]}

KROCHER, O ^{[1
]}

GULDEN, KP ^{[1
]}

LANGE, J ^{[1
]}

BURZLAFF, H ^{[1
]}

机构：

[1] UNIV ERLANGEN NURNBERG,INST ANGEW PHYS,D-91054 ERLANGEN,GERMANY

来源：

TETRAHEDRON | 1994年 / 50卷 / 09期

关键词：

D O I：

10.1016/S0040-4020(01)86996-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis, enantiomer analysis, and configurational assignment of dinaphth[2,1-c:1',2'-e]oxepin-3-(5H)-one, a seven-membered lactone-bridged chiral binaphthalene, is reported. The elucidation of the absolute configuration has been performed, independently by multiple scattering X-ray experiments and by circular dichroism (CD).

引用

页码：2831 / 2840

页数：10

共 32 条

[1] CYCLISATIONS WITH HYDRAZINE .3. SYNTHESES OF PENTAPHENE AND DINAPHTHO[2,1-D-1,2'-F][1,2]DIAZOCINE [J].

BACON, RGR ;

BANKHEAD, R .

JOURNAL OF THE CHEMICAL SOCIETY, 1963, (FEB) :839-&

[2]

BILLY H, 1984, ACTA CRYST A SC, V40, P409

[3] ATROPO-ENANTIOSELECTIVE BIARYL SYNTHESIS BY STEREOCONTROLLED CLEAVAGE OF CONFIGURATIVELY LABILE LACTONE-BRIDGED PRECURSORS USING CHIRAL H-NUCLEOPHILES [J].

BRINGMANN, G ;

HARTUNG, T .

TETRAHEDRON, 1993, 49 (36) :7891-7902

[4]

BRINGMANN G, 1992, LIEBIGS ANN CHEM, P225

[5] THE DIRECTED SYNTHESIS OF BIARYL COMPOUNDS - MODERN CONCEPTS AND STRATEGIES [J].

BRINGMANN, G ;

WALTER, R ;

WEIRICH, R .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (09) :977-991

[6]

BRINGMANN G, 1992, SYNTHESIS-STUTTGART, P433

[7]

BRINGMANN G, 1991, SYNLETT, P581

[8]

BRINGMANN G, 1992, SELECTIVE REACTIONS, P183

[9]

BRINGMANN G, 1994, IN PRESS J ORGANOMET

[10]

BRINGMANN G, 1993, GIT FACHZ LAB, P189

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