Adsorption of alkyl-trichlorosilanes on glass and silicon: A comparative study using sum-frequency spectroscopy and XPS

被引：24

作者：

Lobau, J

Rumphorst, A

Galla, K

Seeger, S

Wolfrum, K

机构：

[1] TECH UNIV MUNICH,DEPT PHYS E11,D-85748 GARCHING,GERMANY

[2] UNIV HEIDELBERG,INST PHYS CHEM,D-69120 HEIDELBERG,GERMANY

来源：

THIN SOLID FILMS | 1996年 / 289卷 / 1-2期

关键词：

chemisorption; infrared spectroscopy; surface phonons and adsorbate vibrations; X-ray photoelectron spectroscopy;

D O I：

10.1016/S0040-6090(96)08925-0

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Chemisorbed films of octadecyltrichlorosilane and propyltrichlorosilane on glass have been studied in a natural laboratory environment. Information on the molecular conformation and orientation is obtained from sum-frequency spectroscopy (SFS). The cleaning procedure preceding the coating process was monitored by SFS and X-ray photoelectron spectroscopy. In-situ monitoring of surface contaminations under normal atmospheric conditions by SFS provides valuable information on the effectiveness of cleaning and activation procedures.

引用

页码：272 / 281

页数：10

共 47 条

[1] SFG STUDY OF 2-DIMENSIONAL ORIENTATION OF SURFACE METHYL-GROUPS ON CADMIUM ARACHIDATE LANGMUIR-BLODGETT-FILMS [J].

AKAMATSU, N ;

DOMEN, K ;

HIROSE, C .

JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (39) :10070-10075

[2] ANOMALOUSLY INTENSE RAMAN-SPECTRA OF PYRIDINE AT A SILVER ELECTRODE [J].

ALBRECHT, MG ;

CREIGHTON, JA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (15) :5215-5217

[3] CONFORMATIONAL BEHAVIOR OF ALKYL CHAINS OF REVERSED PHASES IN HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY [J].

BAYER, E ;

PAULUS, A ;

PETERS, B ;

LAUPP, G ;

REINERS, J ;

ALBERT, K .

JOURNAL OF CHROMATOGRAPHY, 1986, 364 :25-37

[4] DIRECT DIFFUSION MEASUREMENTS OF NAPHTHACENE ON CHEMICALLY DERIVATIZED SILICA-GELS [J].

BJARNESON, DW ;

PETERSEN, NO .

LANGMUIR, 1991, 7 (11) :2821-2826

[5]

BOERIO FJ, 1979, J COLLOID INTERF SCI, V73, P176

[6]

BOHN PW, 1989, PROG ANAL SPECTROSC, V12, P41

[7] ORGANIC-CHEMISTRY AT INTERFACES STUDIED BY OPTICAL 2ND-HARMONIC AND IR-VIS SUM-FREQUENCY GENERATION [J].

BUCK, M .

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 1992, 55 (05) :395-402

[8] EFFECT OF WETTING ON THE REORIENTATION OF ACRIDINE-ORANGE AT THE INTERFACE OF WATER AND A HYDROPHOBIC SURFACE [J].

BURBAGE, JD ;

WIRTH, MJ .

JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (14) :5943-5948

[9] HIGH-RESOLUTION ELECTRON-MICROSCOPY AND SCANNING TUNNELING MICROSCOPY OF NATIVE OXIDES ON SILICON [J].

CARIM, AH ;

DOVEK, MM ;

QUATE, CF ;

SINCLAIR, R ;

VORST, C .

SCIENCE, 1987, 237 (4815) :630-633

[10] HETEROGENEITY OF REVERSED-PHASE CHROMATOGRAPHIC SURFACES - QUENCHING OF SORBED PYRENE FLUORESCENCE [J].

CARR, JW ;

HARRIS, JM .

ANALYTICAL CHEMISTRY, 1987, 59 (21) :2546-2550

← 1 2 3 4 5 →