Catalytic arylation of carbon-carbon double bond followed by N- or O-cyclization

被引：39

作者：

Catellani, M ^{[1
]}

Del Rio, A ^{[1
]}

机构：

[1] Univ Parma, Dept Organ & Ind Chem, I-43100 Parma, Italy

来源：

RUSSIAN CHEMICAL BULLETIN | 1998年 / 47卷 / 05期

关键词：

palladium complexes; catalysis; formation of C-C; C-O; and C-N bonds; cyclization;

D O I：

10.1007/BF02498163

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Under the catalytic action of pallodium, o-hydroxy- or o-amino-substituted aryl iodides oxidatively add to palladium(0), insert strained or rigid olefins, and close the ring between the aliphatic carbon and the ortho-functional group. This reaction occurs under mild conditions in the absence of phosphine ligands in a DMF solution and affords fused dihydrofurans or -pyrroles.

引用

页码：928 / 931

页数：4

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