Palladium nanoparticles supported on polyaniline nanofibers as a semi-heterogeneous catalyst in water

被引：422

作者：

Gallon, Benjamin J. ^{[1
]}

Kojima, Robert W. ^{[1
]}

Kaner, Richard B. ^{[1
]}

Diaconescu, Paula L. ^{[1
]}

机构：

[1] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 38期

关键词：

C-C coupling; nanostructures; palladium; polymers; supported catalysts;

D O I：

10.1002/anie.200701389

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) A tandem catalyst for Suzuki coupling of activated or deactivated aryl chlorides and aryl boronic acids in water and for phenol synthesis from aryl chlorides in 1:1 water/dioxane was obtained by supporting palladium nanoparticles on polyaniline nanofibers (PANI; see TEM image). Thus, 2-phenylphenol was synthesized from 1,2-dichlorobenzene (see equation). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7251 / 7254

页数：4

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